special hazards of potassium thiocyanate

Accidental release measures The reaction of phenylazoalkenes 424 with an excess of potassium thiocyanate in acetic acid produces the cycloadducts 425 that undergo further [3+2]-cycloaddition reaction with thiocyanic acid at the azomethine imine function giving rise to the bicyclic product imidazo[1,5-b][triazole]-2,5-dithiones 41 (Equation 87) <1998SL786>. When solid hydroxylamine is brought into contact with solid potassium permanganate, there is produced immediately a with flame. Pennsylvania Right To Know Components Potassium thiocyanate CAS-No. 206-370-1 Molecular Formula C K N S 1.2. Potassium Thiocyanate 333-20-0 90 - 100% Yes 3. 333-20-0 May cause mild irritation to the skin and eyes. Product Description: Potassium thiocyanate Cat No. Potassium thiocyanate Revision Date Oct-2018 SECTION 2: HAZARDS IDENTIFICATION For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16 2.2. May cause eye, skin, and respiratory tract irritation. * Eye wash fountains should be provided in the immediate work area for emergency use. Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects Ingestion: May cause psychosis, vomiting, disorientation, weakness, low blood pressure, convulsions and death which may be delayed. The story of the thiocyanates began in 1903 with Pauli, who suggested the use of potassium thiocyanate as a hypotensive agent. ECOLOGICAL INFORMATION 12.1 Toxicity no data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential Skin: May cause skin irritation. May cause kidney damage. Hazardous combustion products: Hydrogen cyanide. It is a pseudohalide anion and a sulfur molecular entity. In recent years thiocyanates have been used enthusiastically. : P/7280/50, P/7280/53 Synonyms Potassium rhodanide CAS-No 333-20-0 EC-No. Potassium Thiocyanate 1. Structure, properties, spectra, suppliers and links for: potassium ferrocyanide. Wear full protective equipment, including suitable respiratory protection. 1. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. ... potassium thiocyanate Potassium thiocyanate 2.6 mg/m3 28 mg/m3 170 mg/m3 Ingredient Original IDLH Revised IDLH potassium thiocyanate Not Available Not Available Exposure controls Appropriate engineering View information & documentation regarding Potassium thiocyanate, including CAS, MSDS & more. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. May be harmful if swallowed. May cause irritation. Special controls should be in place for highly toxic chemicals or when significant skin, eye, or breathing exposures are possible. Contains: Potassium thiocyanate 2.3 Other hazards. Potassium Permanganate being conveyed through propylene tube ignited the tube. Potassium permanganate decomposes hydrogen It is an important salt of the thiocyanate anion , one of the pseudohalides . ... individuals who have been informed of the hazards of exposure to Potassium Permanganate. 333-20-0 Potassium Thiocyanate <1.0 % 206-370-1 Hazard Symbols: XN Risk Phrases: 21/22 32 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. Contact with other material may cause a fire. POTASSIUM THIOCYANATE Prepared 05/12/01 By Dr. B. Dunlevy Page 2 of 4 Special fire fighting procedures Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Hazard Identification Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung Product name Potassium thiocyanate for analysis EMSURE® ACS,ISO,Reag. Special Remarks on Fire Hazards: Spontaneously flammable on contact with ethylene glycol. Potential Health Effects Eye: May cause eye irritation. : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Health Hazards! Rabbit oral LDLo: … OSHA. Target Organs: Heart, brain. POTASSIUM page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. It has a role as a human metabolite. 7732-18-5 Revision Date Strong oxidizer. I'm concerned about the information that KSCN can be used to resemble fake blood and stigmata; this may encourage some readers of the article to try this on their own hands and skins, yet the article doesn't mention any of the health risks, although the word "harmful" does appear. 3 Effective date : 12.16.2014 Page 2 of 7 Sodium Thiocyanate, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Potassium Thiocyanate,ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com Control Parameters: 333 - 20 - 0, Potassium thiocyanate, TWA 5 mg/m3 USA. Thiocyanate is a pseudohalide anion obtained by deprotonation of the thiol group of thiocyanic acid. Ph Eur Page 2 of 13 The life science business of Merck operates as MilliporeSigma in the US and Canada Acute toxicity, Category 4, Oral, H302 Acute toxicity, Category 4, Inhalation, H332 Acute toxicity, Category 4, Dermal, H312 Serious eye damage, Category 1, H318 Symptoms may include coughing, shortness of breath. HARMFUL IF SWALLOWED OR INHALED. Special Equipment and Precautions: Use water to cool nearby containers and structures. Wear fully protective impervious suit. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Hazards Identification. The compound has a low melting point relative to most other inorganic salts. Product Identification Synonyms: Potassium sulfocyanate; Potassium thiocyanide; Thiocyanic acid, potassium salt; Potassium isothiocyanate CAS No. 110760-Potassium thiocyanate, ACS Version: 3 Revision date: 19/04/2016 Page 2 of 8 Print date: 19/04/2016 -Continued on next page.- P362+P364 Take off contaminated clothing and wash it before reuse. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA 6. Unusual fire and explosions hazards Emits toxic fumes under fire conditions. High purity, submicron and nanopowder forms may be considered. Product name : Potassium thiocyanate Product Number : 207799 Brand : Sigma-Aldrich Index-No. Uses advised against No Information available 1.3. Product: Potassium Thiocyanate Revision Date: 07/17/2013 3/7 Special Protective Equipment As in any fire, wear MSHA/NIOSH approved (or equivalent) self-contained positive pressure Caution! Human oral LDLo: 80 mg/kg, hallucinations, distorted perceptions, convulsions, muscle weakness. 7732-18-5 Revision Date Potassium thiocyanate 333-20-0 1989-12-01 New Jersey Right To Know Components Water CAS-No. 333-20-0 Revision Date 1989-12-01 New Jersey Right To Know Components Potassium thiocyanate CAS-No. This is an example of a custom, not too rare, of reviving and injecting new enthusiasm into ancient discarded treatments. Duration of … Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) ... Potassium Thiocyanate (Potassium Rhodanide) is generally immediately available in most volumes. May cause methemoglobinemia. It has a role as a human metabolite. Potassium Thiocyanate 333-20-0 < 0.2 Not Available Not Available Not Available Not Available Water, Deionized 7732-18-5 Balance Not Available Not Available Not Available Not Available Section 3: Hazard Identification Emergency Overview: Non-flammable, non-toxic, non-corrosive. SAF-T-DATA(tm) Ratings (Provided here ... Special Information: Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Chemical Product and Company information. SECTION 6. 4.3 Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Dry powder 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Potassium oxides 5.3 Advice for firefighters Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung irritant). ACCIDENTAL RELEASE MEASURES 7757-79-1 Potassium nitrate >99 231-818-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white. SARA 311/312 Hazards No SARA Hazards Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Danger! Hazards Identification Emergency Overview-----WARNING! 5.2 Special hazards arising from the substance or mixture ... Stomach - Irregularities - Based on Human Evidence (Potassium thiocyanate) 12. Section 6. Special hazards arising from the substance or mixture No additional information available 5.3. Special hazards arising from the substance or mixture No additional information available 5.3. EUH statements: EUH032 Contact with acids liberates very toxic gas. 3. Potassium thiocyanate 333-20-0 100 Toxicological Data on Ingredients: Potassium thiocyanate: ORAL (LD50): Acute: 854 mg/kg [Rat]. Hygroscopic Pennsylvania Right To Know Components Water CAS-No. The probable lethal dose is … Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) Nitrogen oxides (NOx) Potassium oxide Advice for firefighters Protective equipment: Wear self-contained respirator. Specific Hazards: Thermal decomposition of potassium thiocyanate may produce toxic hydrogen cyanide fumes. 594 mg/kg [Mouse]. Inhalation: Causes irritation to the respiratory tract. : 615-030-00-5 CAS-No. Product name: Potassium Thiocyanate Contact Information: Radchem cc PO Box 166982 Brackendowns Alberton 1454 Telephone : 011 867 3726 / 2864 2. Data on potassium thiocyanate, a very similar chemical: Human oral TDLo: 428 mg/kg, toxic psychosis, hallucinations, distorted perceptions, gastritis. Product name : Potassium Thiocyanate CAS-No. Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of use or handling. Sigma-Aldrich offers a number of Potassium thiocyanate products. : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Potassium Thiocyanate Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier:Potassium thiocyanate ... 5.2 Special hazards arising from the substance or mixture: SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. 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